The following 40-man roster players have less than five years service time and are out of minor league options. That means they must clear waivers before being sent to the minors. I've included players on multiyear deals. This list was compiled through MLBTR's sources.
Angels
Bobby Cassevah, Ernesto Frieri, Kevin Jepsen, Brad Mills, Jerome Williams
Astros
Chris Carter, Tyler Greene, Lucas Harrell, Phil Humber, Fernando Martinez, Justin Maxwell, Wesley Wright
Athletics
Daric Barton, Travis Blackley, Jerry Blevins, Josh Donaldson, Brandon Moss, Pat Neshek, Chris Resop, Adam Rosales
Blue Jays
Emilio Bonifacio, Brett Cecil, Jeremy Jeffress, Luis Perez, Esmil Rogers, Sergio Santos
Braves
Juan Francisco, Cristhian Martinez, Ramiro Pena, Jordan Schafer, Anthony Varvaro
Brewers
Jeff Bianchi, Mat Gamel, Chris Narveson, Mark Rogers
Cardinals
None
Cubs
Michael Bowden, Welington Castillo, Jeff Samardzija, Luis Valbuena, Travis Wood
Diamondbacks
None
Dodgers
Scott Elbert, Ronald Belisario, A.J. Ellis
Giants
Conor Gillaspie, Joaquin Arias, Gregor Blanco, Yusmeiro Petit, Jose Mijares
Indians
Ezequiel Carrera, David Huff
Mariners
Josh Kinney, Robert Andino, Casper Wells, Mike Carp (designated for assignment 2-12-13)
Marlins
Mike Dunn, Gorkys Hernandez, Wade LeBlanc, Justin Ruggiano
Mets
Brandon Hicks
Nationals
Roger Bernadina, Tyler Clippard, Ross Detwiler, Henry Rodriguez, Carlos Rivero
Orioles
Chris Davis, Jim Johnson, Troy Patton, Nolan Reimold, Pedro Strop, Taylor Teagarden, Tommy Hunter, Chris Tillman
Padres
Cameron Maybin, Eric Stults, Joe Thatcher, Dale Thayer
Phillies
John Mayberry, Kevin Frandsen
Pirates
Jeanmar Gomez, Chris Leroux, James McDonald, Mark Melancon, Charlie Morton, Garrett Jones, Travis Snider, Jose Tabata
Rangers
Julio Borbon, Michael Kirkman
Rays
Jake McGee, Jeff Niemann, Jose Lobaton, Sam Fuld, Matt Joyce, Cesar Ramos
Red Sox
Felix Doubront, Andrew Miller, Franklin Morales, Clayton Mortensen, Pedro Ciriaco
Reds
Jose Arredondo, Homer Bailey, Jason Donald, Jack Hannahan, Xavier Paul, Alfredo Simon
Rockies
Carlos Gonzalez, Chris Nelson, Eric Young, Edgmer Escalona
Royals
Luke Hochevar, Luis Mendoza, Felipe Paulino, Juan Gutierrez, Guillermo Moscoso, Brett Hayes, George Kottaras, Jarrod Dyson, Elliot Johnson
Tigers
None
Twins
Trevor Plouffe, Josh Roenicke, Anthony Swarzak, Tim Wood
White Sox
Hector Gimenez, Leyson Septimo, Angel Sanchez
Yankees
Francisco Cervelli, Clay Rapada, Chris Stewart